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Two new reactive, very powerful organic peroxides, dimethyldioxirane and methyl(trifluoromethyl)dioxirane (4), have been introduced. 81 - 83 The latter is more reactive and can be used more conveniently.84,85 Acyclic alkanes give a mixture of isomeric ketones on oxidation with methyl(trifluoromethyl)dioxirane,84,85 while cyclohexanone is the sole product in the oxidation of cyclohexane (99% selectivity at 98% conversion).85 With the exception of norbomane, which undergoes oxidation at the secondary C-2 position, highly selective tertiary hydroxylations can be carried out with regioselectivities in the same order of magnitude as in oxidations by peracids. 85- 87 A similar mild and selective tertiary hydroxylation by perfluorodialkyloxaziridines was also reported. 88 Oxidation with dioxiranes is highly stereoselective: 85 The WEEKDAY function accepts a date argument and returns an integer between 1 and 7 that corresponds to the day of the week. 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