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olism, viz. degraded to phenolic acid metabolites (57). The degradation products of procyanidins have not yet been fully characterized, and more work on the possible biological effects of the metabolites is warranted. Research so far indicates that the concentration of epicatechin in cocoa is the major factor to explain the association of cocoa and health (53). 9.2.2.2 Tea Tea (Camellia sinensis) is one of the most popular beverages consumed worldwide. Green and black teas can be considered the major categories, with the latter representing >75% of the world production and popularity dominating among North American and European consumers (58). However, production today is also diversifying into speciality teas such as white tea, fruit, herbal and scented teas, and other speci c tea blends. 9.2.2.2.1 Chemical Changes during Processing The fundamental steps of tea processing are relatively straightforward (Fig. 9.6). Green tea is prepared by steaming (at about 100 C) the tea leaves or pan- red (as high as 230 C) to produce Japanese green tea or Chinese green tea, respectively. These thermal treatments inactivate enzymes (polyphenol oxidases), avoiding further biochemical reactions (condensation/polymerization) in the tea leaves, with concomitant change in the chemical pattern. After heat treatment, the tea leaves are subjected to subsequent rolling and drying processes to afford a dry product. White tea is produced from the buds of young leaves, steamed and dried. The composition of the tea leaf is characterized by a high amount of polyphenols (mainly avonoids), with an average content of 28% avonoids on a dry weight basis (58). Importantly, the tea classes differ in their relative avonoid composition, and these include catechins, thea avins, thearubigins, and avonol glycosides.

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80 90% 1 2%

10 19 7 45

White tea Partially Steamed Air dried Catechins Theaflavins& Thearubigens Green tea Steamed or Pan-fired Rolling & drying Rolling & drying Final firing Final firing Final firing Dolong tea Withering Parching 5 18%

9

78 85%

Security 2 1 1 2 1 2 1 1 1 1 2 2 2 1 2 2 3 2 7 31 10 1 1 2 1 1 1 1 2 36 3 1 3 2 2 11 1 2 1 2 16 7 2 12 1 1 2 1 2 2 1 1 3 14 3 4 3 2

Rolling or CTC* (Fermentation)

Figure 9.6 Overview of traditional tea manufacture and its impact on polyphenol content (*CTC = crushing/tearing/curling). See color insert.

1 1 4

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The tea leaf contains a polyphenol oxidase enzyme that catalyzes the aerobic oxidation of catechins upon disruption of the leaf cell structure This is a key step in the manufacture of black tea and is in fact a drying period after rolling or crushing/tearing/curling (CTC) to initiate the enzymic reaction, and is clearly distinct from the yeast-mediated alcoholic fermentation (59) The different quinones produced by enzymatic oxidation undergo condensation reactions resulting in a series of compounds, including bis avanols, thea avins, and thearubigens, which contribute to the major organoleptic properties of black tea The steps of black tea manufacture are designed to achieve oxidation of the tea catechins and produce a product of optimal quality avor and color (60) Thus, the pattern of polyphenols in tea depends on the degree of oxidation (61).

In this chapter we cover the implementation of sequential-mode JPEG encoders In general, the process for creating a JPEG file is the reverse of the decoding process A major difference between encoding and decoding is that encoding requires several choices to be made while in decoding you take what you get The endcoding choices include compression parameters, Huffman code generation, and block ordering

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Oolong tea, on the other hand, is less oxidized, and prepared by ring the leaves after rolling to terminate the oxidative processes, thereby resembling more closely green tea (Fig 96) Catechins are the major avonoids in fresh unprocessed green tea leaves, the principal compounds being ( )-epigallocatechin (EGC), ( )-epicatechin gallate (ECG), and ( )-epigallocatechin gallate (EGCG) These are subjected to oxidative process during tea manufacture, procuring the corresponding quinones by action of polyphenol oxidase These reactive compounds can readily dimerize or polymerize via radical-driven phenol-coupling reactions to form polyphenolic compounds as typically found in oolong and black teas The major condensation compounds are thea avins and the polymeric thearubigens, the former giving tea the characteristic bright orange-red color of black tea In fact, thea avins account for 1 2% dry weight of the water-extractable fraction, and in percentage of total phenolics represents >50% (59) (Fig 97).

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Thearubigens, which can reach concentrations of 10 20% on a dry matter basis, represent the major oxidation products of catechins during fermentation, increasing with fermentation time with a concomitant loss of catechins such.

90.0 80.0 70.0 60.0 % 50.0 40.0 30.0 20.0 10.0 0.0

8/15

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